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Project Code [2009-PhD-ET-1]
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Project title
Catalysts for the promotion of green selective oxidation reactions
Primary Funding Agency
Environmental Protection Agency
Co-Funding Organisation(s)
n/a
Lead Organisation
University College Dublin (UCD)
Lead Applicant
James Sullivan
Project Abstract
We will synthesise, characterise, apply and optimise supported metallic catalysts containing Pd nanoparticles for H2O2 production (from H2 + O2) and do the same for mesoporous Ti-containing materials to catalyse selective epoxidation of alkenes using H2O2. We will then combine these catalysts to form a material to selectivity epoxidise alkenes using O2(g)/H2(g) as a green oxidant. These processes would have far lower E-factors and higher atom efficiencies than traditional stoichiometric oxidations.The syntheses will involve nanoparticle preparation and deposition and the formation of template-derived mesoporous oxides. Characterisations will include TEM, SEM/EDX, FTIR and Raman spectroscopy, physisiorption and chemisorption measurements.
Grant Approved
�95,000.00
Research Hub
Green and Circular Economy
Research Theme
Waste and Resources Management
Initial Projected Completion Date
01/09/2012