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Project Code [2008-ET-MS-2-S2]
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Project title
Micro-photochemistry - a New Resources-Efficient R&D Approach
Primary Funding Agency
Environmental Protection Agency
Co-Funding Organisation(s)
n/a
Lead Organisation
Dublin City University (DCU)
Lead Applicant
Kieran Nolan
Project Abstract
The proposal describes innovative and resources-efficient approaches to organic synthesis and chemical analysis. Emerging Micro-photochemistry combines organic photochemistry and microprocess engineering with advances in LED technology. Novel micro-photoreactors for predominantly homogeneous reactions will be based on microfluidic chip technology. LED-panels will be used as optimal light sources. The superiority of micro-photochemistry over conventional techniques will be demonstrated for different model reactions. Solventefficient Solid-Phase Extraction with Capture and Photochemical Release will use for the first time covalent bond formation to extract analyte onto a monolithic microcolumn and photochemical release to elute it by an external light trigger. The Micro-photochemistry project will established a strong research excellence team at DCU. It will lead to a new industry-academia partnership, which will develop the concept of miniaturised photoreactors for applications within the chemical industry. Its innovative character will furthermore fuel attention within the chemical community. It is expected that the micro-photochemistry project will result in a total of 10-15 high-profile publications. The dual nature of the Micro-photochemistry concept, i.e. synthetic vs. analytical, will allow rapid technology transfer to replace existing technical processes. Due to their compact sizes Micochip photoreactors will operate resource-efficient. In combination with LEDs, Microphotoreactions are expected to yield higher selectivities.
Grant Approved
�349,823.70
Research Hub
Green and Circular Economy
Research Theme
Waste and Resources Management
Initial Projected Completion Date
01/09/2011