What are PFAS?

Photo by Caspar Rae on Unsplash

PFAS is an abbreviation for per- and poly-fluoroalkylated substances.

  • They are a very large group of man-made chemicals that have multiple fluorine atoms attached to a carbon chain. Approximately 4,700 PFAS have been identified to date.
  • PFAS have been used in industrial and consumer products since the 1950s due to their physical and chemical properties. These properties include water and oil resistance, chemical and heat stability, friction reduction and surface tension lowering (also known as surfactant properties - results in increased spreadability of materials).
  • They can be found in many everyday products – outdoor clothing and equipment, textiles, paints, food packaging, photographic coatings, non-stick coatings on cookware as well as fire-fighting foam.
  • They can have harmful effects on human and animal health and stay in the environment and in our bodies for long periods of time where they can increase in concentration. They are often referred to as “forever chemicals”.
  • Some PFAS have been linked to an increased risk of cancer, high cholesterol, reproductive disorders, hormonal disruption (also known as endocrine disruption) and weakening of the immune system.
  • Human and environmental exposure to PFAS can arise from contaminated water and food, PFAS-containing consumer products, household dust and air as well as the reuse of PFAS contaminated sewage sludge as fertiliser resulting in PFAS pollution in soil and crops.

 

What is being done about PFAS?

1. PFAS restriction

Two PFAS are currently restricted under the international Stockholm Convention on POPs and the EU POPs Regulation

  • PFOS (perfluoroctanesulfonic acid) and its derivatives since 2009/2010.
  • PFOA (perfluorooctanoic acid), its salts and related compounds, as of 4th July 2020. The current list of PFOA and PFOA-related substances is available in the links below. Please note that this list is under review and will be updated when more information becomes available.
  • Time-limited exemptions exist for some specific uses of PFOA including PFOA in fire-fighting foam, photolithography and in semiconductor manufacturing and in invasive and implantable medical devices, until July 2025. Further details of the allowed exemptions are provided in the table at the end of this page. If availing of an exemption, contact the EPA at pops@epa.ie.
  • If you have stockpiles containing PFOA or PFOA-related substances on site, with an aggregate volume of >50kg and above threshold concentrations you must notify the EPA annually. The concentrations are:

>0.025 mg for PFOA and its salts; and
>0.0001 mg/kg for any individual PFOA-related compound or a combination of PFOA-related compounds.

The deadline for receipt of reports of stockpiles has been extended to 30 November 2021. Access to the reporting system will be via the EPA’s Environmental Data Exchange Network portal. The information requested will include details of:

  • Stockpile nature/use – for example installed within fire suppression systems (including fire extinguishers), medical device etc., please note – may be a combination of uses;
  • Concentration of PFOA and/or PFOA-related substance(s) within each stockpile component (the 50kg limit refers to an aggregate weight and so may be made up of “sub-stockpiles”);
  • Location & quantity of stockpile;
  • Contact details of person(s) making the notification;
  • How the stockpile is managed and stored; and
  • Disposal details where sent off site for disposal - the following contractors are licenced by the EPA to handle hazardous waste and may be able to offer physio-chemical treatment of POPs waste (there may also be others):
    • Indaver Ireland limited
    • Enva Ireland Limited
    • Veolia Environmental Services Technical Solutions limited
    • Rilta Environmental Limited

Further information on reporting can be found in the EPA’s factsheet on PFOA in fire-fighting foams and in our frequently asked questions.

 

Other PFAS are being evaluated for restriction:

PFAS group/PFAS acronym

PFAS nameLegal basis for restriction
  PFHxS perfluorohexane sulfonic acid Stockholm Convention
  PFHxA undecafluorohexanoic acid Stockholm Convention & REACH

C9-C14

PFCAs (perfluorinated carboxylic acids)






PFNA perfluorononan-1-oic acid REACH
PFDA nonadecafluorodecanoic acid REACH
PFUnDA henicosafluoroundecanoic acid REACH
PFDoDA tricosafluorododecanoic acid REACH
PFTrDA pentacosafluorotridecanoic acid REACH
PFTDA heptacosafluorotetradecanoic acid REACH
  HFPO-DA 2,3,3,3-tetrafluoro-2-(heptafluoropropoxy)propionic acid its salts and its acyl halides (GenX) REACH SVHC1 candidate list
  PFBS perfluorobutane sulfonic acid and its salts REACH SVHC1 candidate list

Note1: ECHA (The European Chemicals Agency) is driving the restriction of several other PFAS by placing them on the REACH (Registration, Evaluation, Authorisation and restriction of Chemicals) candidate list of substances of very high concern (SVHC).

 

  • Germany, the Netherlands, Norway, Sweden and Denmark, are proposing a ban on all PFAS, except for essential uses under REACH. It is expected that the proposal will be submit to ECHA by 15 July 2022.
  • The EU Green Deal Chemicals Strategy for Sustainability has prioritised the regulation of PFAS as a chemical group.
  • The new EU Drinking Water Directive (EU 2020/2184) includes limits for total PFAS of 0.5 µg/L and the sum of 20 PFAS of most concern of 0.1 µg/L .

2. POPs National Implementation Plan

The EPA’s Action Plan on POPs within the POPs National Implementation Plan includes several tasks relating to PFAS which are underway including:

  • Determine the extent of the risks posed by PFAS in Ireland e.g. from PFAS in fire-fighting foam or PFAS in landfill leachate.
  • Investigate the extent of environmental contamination in Ireland with PFAS.
    • A Priority and Priority Hazardous Substances Scoping Study carried out in 2017 and 2018 detected PFAS in some rivers, lakes and fish.
    • Since 2019, the EPA routinely monitors water for PFOA, as well as PFOS, as part of the Water Framework Directive monitoring of rivers and lakes.
    • In 2020, the EPA monitored groundwater and detected very little PFAS. The More detailed analysis of potentially higher-risk waterbodies for PFAS is underway.
  • A coordinated approach across the EPA and with external public bodies in monitoring the environment for PFAS.
  • Awareness raising across the EPA, with other public bodies and stakeholders and with the public about POPs, in particular, newer POPs such as PFAS.

3. PFAS in fire-fighting foams

Photo by Úna Prendergast

PFAS are commonly used in fire-fighting foams, particularly ‘Class B’ foams which are used to combat flammable fuel fires.

  • The EPA carried out a desktop study and survey in 2020 on the use of PFAS foams in Ireland which highlighted the wide-range, and often large volumes of PFAS-containing foams used by industry and fire services. This report includes information on PFAS-free and PFAS-containing fire-fighting foams and is available below.
  • The EPA also undertook a in 2020 to investigate potential hotspots for PFAS contamination from fire-fighting foams. Water, soil, sediment and vegetation samples were obtained from four fire-training sites. Exceedances of adopted human health, environmental quality and ecological screening criteria were detected, mainly in water samples.
  • The EPA are continuing to engage with industry and the fire services about the use and disposal of PFAS foams. An EPA guidance booklet and infographic is available for users, suppliers and waste operators.
  • Further work is underway by the EPA to assess the risks posed by the release and disposal of PFAS-containing foams and to identify additional high-risk sites. 
  • The European Commission DG Environment and ECHA published a report on the use of PFAS and fluorine-free alternatives in fire-fighting foams in 2020.
  • ECHA will submit a restriction proposal for PFAS used in firefighting foams in October 2021. This use is not included in the wide PFAS restriction proposed by the five European countries. 

4. EPA-funded PFAS research

Several EPA-funded research projects have assessed the risks posed by PFAS to human health and the environment in Ireland. For example:

  • The ELEVATE study investigated human exposure to PFAS with PFAS being identified in indoor air and dust, drinking water and human milk samples. Levels of PFAS in human milk did not represent a health concern for nursing infants but modelling indicated that adult exposure for PFAS may exceed the provisional EFSA tolerable weekly intake value or TWI. The researchers recommended further studies on dietary exposure to PFAS in Ireland.
  • The FUEL study investigated the risk posed from PFAS in landfills. Landfill leachate and the surrounding air, soil & groundwater were investigated for PFAS. A potential risk of PFAS contamination from landfills to the surrounding groundwater was identified as well as to waterways and land from disposal of leachate via waste water treatment plants. Further monitoring of landfills was recommended.

Find out more

PFOA restriction under EU POPs Regulation

EU report on the use of PFAS and fluorine-free alternatives in fire-fighting foams

EPA Guidance Booklet & Infographic on PFAS in fire-fighting foams

EEA Emerging chemical risks in Europe  - PFAS

ECHA - Perfluoroalkyl chemicals (PFAS)

European Green Deal Chemicals Strategy

EU Drinking Water Directive (EU) 2020/2184

EPA Water Framework Directive Datasets

EPA report on PFAS in fire-fighting foams

EPA report on PFAS and BFR monitoring at fire-training sites

EPA-funded POPs research projects: ELEVATE, FUEL, SAFER, WAFER

Current list of PFOA and PFOA-related substances

 

For any queries relating to PFAS, please email pops@epa.ie 

Specific exemptions on PFOA, its salts and PFOA-related compounds

 

Exemption detailsDeadline
Photolithography or etch processes in semiconductor manufacturing 4 July 2025
Photographic coatings applied to films 4 July 2025
Textiles for oil- and water-repellency for the protection of workers from dangerous liquids that comprise risks to their health and safety 4 July 2023
Invasive and implantable medical devices 4 July 2025

Fire-fighting foam for liquid fuel vapour suppression and liquid fuel fire (Class B fires) already installed in systems, including both mobile and fixed systems, subject to the following conditions:

(a) fire-fighting foam that contains or may contain PFOA, its salts and/or PFOA-related compounds shall not be used for training;

(b) fire-fighting foam that contains or may contain PFOA, its salts and/or PFOA-related compounds shall not be used for testing unless all releases are contained;

(c) as from 1 January 2023, uses of fire-fighting foam that contains or may contain PFOA, its salts and/or PFOA-related compounds shall only be allowed in sites where all releases can be contained;

(d) fire-fighting foam stockpiles that contain or may contain PFOA, its salts and/or PFOA-related compounds shall be managed in accordance with Article 5

4 July 2025
Use of perfluooroctyl bromide containing perfluoroctyl iodide for the purpose of producing pharmaceutical products Review and assessment by 31 December 2026, every four years thereafter and by 31 December 2036

Manufacture of polytetrafluoroethylene (PTFE) and polyvinylidene fluoride (PVDF) for the production of:

(I) high-performance, corrosion-resistant gas filter membranes, water filter membranes and membranes for medical textiles,

(ii) industrial waste heat exchanger equipment,

(iii) industrial sealants capable of preventing leakage of volatile organic compounds and PM2.5 particulates

4 July 2023